H2N2V1, Main, Exploration, bibRecord, 001B11

Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3

Identifieur interne : 001B11 ( Main/Exploration ); précédent : 001B10; suivant : 001B12

Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3

Auteurs : A. Kabadou [Tunisie] ; R. Ben Hassen [Tunisie] ; A. Ben Salah [Tunisie] ; T. Jouini [Tunisie]

Source :

physica status solidi (b) [ 0370-1972 ] ; 1998-08.

RBID : ISTEX:BD08F83467736F2047C06253472C1E20575AE755

English descriptors

Teeft :
- Activation energies delt, Chlorine atoms, Complex impedance method, Crystal structure, Cshgcl3, Dielectric, Dielectric measurements, Electrical properties, Equivalent coordination bonds, Frequency range, Hassen, Hgcl2, Hgcl2 libration, High temperatures, Hydrogen atoms, Impedance, Inverse temperature, Jouini, Kabadou, Lattice mode translation, Phase transition, Phase transitions, Raman, Raman spectra, Room temperature, Room temperature phase, Salah, Same structure, Slow increase, Space group, Temperature dependence, Temperature phase, Title compound crystallises, Translational mode.

Abstract

The title compound crystallises in the space group P32 and has the unit cell dimensions a = 13.295(11) Å, c = 9.419(8) Å, V = 1441.82(2), Z = 9, Dexp = 4.17, Dcalc = 4.153. The structure at room temperature is considered as distorted perovskite tentatively with R = 0.057 and WR2= 0.153 for 700 observed reflections. The dielectric permittivity measured in the frequency and temperatures ranges 103 to 106 Hz and 307 to 613 K, respectively, reveals a transition at T = 449 K. Transport properties in this material appear to be due to the high mobility of NH4+ in the tunnels.

Url:

https://api.istex.fr/ark:/67375/WNG-8NZBSQK2-G/fulltext.pdf

DOI: 10.1002/(SICI)1521-3951(199808)208:2<387::AID-PSSB387>3.0.CO;2-Y

Affiliations:

Tunisie

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 000046
to stream Istex, to step Curation: 000046
to stream Istex, to step Checkpoint: 000906
to stream Main, to step Merge: 001B66
to stream Main, to step Curation: 001B11

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3</title>
<author><name sortKey="Kabadou, A" sort="Kabadou, A" uniqKey="Kabadou A" first="A." last="Kabadou">A. Kabadou</name>
</author>
<author><name sortKey="Ben Hassen, R" sort="Ben Hassen, R" uniqKey="Ben Hassen R" first="R." last="Ben Hassen">R. Ben Hassen</name>
</author>
<author><name sortKey="Ben Salah, A" sort="Ben Salah, A" uniqKey="Ben Salah A" first="A." last="Ben Salah">A. Ben Salah</name>
</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. Jouini</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:BD08F83467736F2047C06253472C1E20575AE755</idno>
<date when="1998" year="1998">1998</date>
<idno type="doi">10.1002/(SICI)1521-3951(199808)208:2<387::AID-PSSB387>3.0.CO;2-Y</idno>
<idno type="url">https://api.istex.fr/ark:/67375/WNG-8NZBSQK2-G/fulltext.pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000046</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000046</idno>
<idno type="wicri:Area/Istex/Curation">000046</idno>
<idno type="wicri:Area/Istex/Checkpoint">000906</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000906</idno>
<idno type="wicri:doubleKey">0370-1972:1998:Kabadou A:crystal:structure:and</idno>
<idno type="wicri:Area/Main/Merge">001B66</idno>
<idno type="wicri:Area/Main/Curation">001B11</idno>
<idno type="wicri:Area/Main/Exploration">001B11</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main">Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3</title>
<author><name sortKey="Kabadou, A" sort="Kabadou, A" uniqKey="Kabadou A" first="A." last="Kabadou">A. Kabadou</name>
<affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038</wicri:regionArea>
<wicri:noRegion>Sfax‐3038</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ben Hassen, R" sort="Ben Hassen, R" uniqKey="Ben Hassen R" first="R." last="Ben Hassen">R. Ben Hassen</name>
<affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038</wicri:regionArea>
<wicri:noRegion>Sfax‐3038</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ben Salah, A" sort="Ben Salah, A" uniqKey="Ben Salah A" first="A." last="Ben Salah">A. Ben Salah</name>
<affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038</wicri:regionArea>
<wicri:noRegion>Sfax‐3038</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. Jouini</name>
<affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Cristallochimie, Faculté des Sciences, Tunis‐1060 le Belvédère</wicri:regionArea>
<wicri:noRegion>Tunis‐1060 le Belvédère</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">physica status solidi (b)</title>
<title level="j" type="alt">PHYSICA STATUS SOLIDI B</title>
<idno type="ISSN">0370-1972</idno>
<idno type="eISSN">1521-3951</idno>
<imprint><biblScope unit="vol">208</biblScope>
<biblScope unit="issue">2</biblScope>
<biblScope unit="page" from="387">387</biblScope>
<biblScope unit="page" to="395">395</biblScope>
<biblScope unit="page-count">9</biblScope>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Berlin</pubPlace>
<date type="published" when="1998-08">1998-08</date>
</imprint>
<idno type="ISSN">0370-1972</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0370-1972</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Activation energies delt</term>
<term>Chlorine atoms</term>
<term>Complex impedance method</term>
<term>Crystal structure</term>
<term>Cshgcl3</term>
<term>Dielectric</term>
<term>Dielectric measurements</term>
<term>Electrical properties</term>
<term>Equivalent coordination bonds</term>
<term>Frequency range</term>
<term>Hassen</term>
<term>Hgcl2</term>
<term>Hgcl2 libration</term>
<term>High temperatures</term>
<term>Hydrogen atoms</term>
<term>Impedance</term>
<term>Inverse temperature</term>
<term>Jouini</term>
<term>Kabadou</term>
<term>Lattice mode translation</term>
<term>Phase transition</term>
<term>Phase transitions</term>
<term>Raman</term>
<term>Raman spectra</term>
<term>Room temperature</term>
<term>Room temperature phase</term>
<term>Salah</term>
<term>Same structure</term>
<term>Slow increase</term>
<term>Space group</term>
<term>Temperature dependence</term>
<term>Temperature phase</term>
<term>Title compound crystallises</term>
<term>Translational mode</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The title compound crystallises in the space group P32 and has the unit cell dimensions a = 13.295(11) Å, c = 9.419(8) Å, V = 1441.82(2), Z = 9, Dexp = 4.17, Dcalc = 4.153. The structure at room temperature is considered as distorted perovskite tentatively with R = 0.057 and WR2= 0.153 for 700 observed reflections. The dielectric permittivity measured in the frequency and temperatures ranges 103 to 106 Hz and 307 to 613 K, respectively, reveals a transition at T = 449 K. Transport properties in this material appear to be due to the high mobility of NH4+ in the tunnels.</div>
</front>
</TEI>
<affiliations><list><country><li>Tunisie</li>
</country>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Kabadou, A" sort="Kabadou, A" uniqKey="Kabadou A" first="A." last="Kabadou">A. Kabadou</name>
</noRegion>
<name sortKey="Ben Hassen, R" sort="Ben Hassen, R" uniqKey="Ben Hassen R" first="R." last="Ben Hassen">R. Ben Hassen</name>
<name sortKey="Ben Salah, A" sort="Ben Salah, A" uniqKey="Ben Salah A" first="A." last="Ben Salah">A. Ben Salah</name>
<name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. Jouini</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001B11 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001B11 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    H2N2V1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:BD08F83467736F2047C06253472C1E20575AE755
   |texte=   Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3
}}

This area was generated with Dilib version V0.6.33.
Data generation: Tue Apr 14 19:59:40 2020. Site generation: Thu Mar 25 15:38:26 2021

	Serveur d'exploration H2N2
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration H2N2

Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3

Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri